The Mighty Avengers (2007) #36
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Earth's Mightiest Heroes joined forces to take on threats that were too big for any one hero to tackle. With a roster that has included Captain America, Iron Man, Ant-Man, Hulk, Thor, Wasp and dozens more over the years, the Avengers have come to be regarded as Earth's No. 1 team.
With the end of the Vietnam War, John Walker thought his dreams of becoming a war hero had also ended, until he learned of the Power Broker, who could give anyone superhuman powers, which Walker used to first become Super-Patriot and later, U.S. Agent.
Arguably the greatest and certainly the most horrific creation of scientific genius Dr. Henry Pym, Ultron is a criminally insane rogue sentient robot dedicated to conquest and the extermination of humanity.