Defenders (1972) #46
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Characters
Caught in a gamma bomb explosion while trying to save the life of a teenager, Dr. Bruce Banner was transformed into the incredibly powerful creature called the Hulk. An all too often misunderstood hero, the angrier the Hulk gets, the stronger the Hulk gets.
Bitten by a radioactive spider, high school student Peter Parker gained the speed, strength and powers of a spider. Adopting the name Spider-Man, Peter hoped to start a career using his new abilities. Taught that with great power comes great responsibility, Spidey has vowed to use his powers to help people.
Valkyrie (Samantha Parrington)
Amora magically transformed Samantha Parrington into a raging, man-hating facsimile of the Asgardian warrior goddess Brunnhilde the Valkyrie, whose form and might Amora could replicate at will, having trapped Brunnhilde's soul in a mystical crystal centuries earlier.