Thor (1998) #14
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Wounded, captured and forced to build a weapon by his enemies, billionaire industrialist Tony Stark instead created an advanced suit of armor to save his life and escape captivity. Now with a new outlook on life, Tony uses his money and intelligence to make the world a safer, better place as Iron Man.
Despondent and hopeless after it was discovered that she was not, in fact, Spider-Woman, Mary MacPherran encountered Doctor Doom, who offered her a chance to become superpowered in exchange for joining his army, to which Mary readily agreed, and Doom transformed her into Titania.