Avengers Annual (1967) #20
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Earth's Mightiest Heroes joined forces to take on threats that were too big for any one hero to tackle. With a roster that has included Captain America, Iron Man, Ant-Man, Hulk, Thor, Wasp and dozens more over the years, the Avengers have come to be regarded as Earth's No. 1 team.
As the Norse God of thunder and lightning, Thor wields one of the greatest weapons ever made, the enchanted hammer Mjolnir. While others have described Thor as an over-muscled, oafish imbecile, he's quite smart and compassionate. He's self-assured, and he would never, ever stop fighting for a worthwhile cause.