Amazing Spider-Man Annual (1964) #16
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Vowing to serve his country any way he could, young Steve Rogers took the super soldier serum to become America's one-man army. Fighting for the red, white and blue for over 60 years, Captain America is the living, breathing symbol of freedom and liberty.
Peter Parker's first true love, Gwen Stacy was killed during a rescue attempt by Spider-Man, the guilt from which Peter has never overcome.
Wounded, captured and forced to build a weapon by his enemies, billionaire industrialist Tony Stark instead created an advanced suit of armor to save his life and escape captivity. Now with a new outlook on life, Tony uses his money and intelligence to make the world a safer, better place as Iron Man.
Mary Jane Watson was the guiding light in Peter Parker's life, and their love had overcome countless obstacles.
Bitten by a radioactive spider, high school student Peter Parker gained the speed, strength and powers of a spider. Adopting the name Spider-Man, Peter hoped to start a career using his new abilities. Taught that with great power comes great responsibility, Spidey has vowed to use his powers to help people.
The radiation that mutated Reed Richards, Sue Storm and Johnny Storm into superhuman beings had also mutated Ben Grimm, transforming him into a grotesque, rock-hided strongman dubbed the Thing.
As the Norse God of thunder and lightning, Thor wields one of the greatest weapons ever made, the enchanted hammer Mjolnir. While others have described Thor as an over-muscled, oafish imbecile, he's quite smart and compassionate. He's self-assured, and he would never, ever stop fighting for a worthwhile cause.