Ultimate Spider-Man (2000) #70
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Peter’s relatively normal life changed abruptly during a school trip to Osborn Industries, Inc, where the company had been working on a super soldier serum, the Oz Compound; a spider exposed to it escaped and bit Peter before it was destroyed.
He claims he is the legendary Norse thunder deity Thor, sent to Earth by his father Odin, but official records say he is Thorlief Golmen, who stole his scientist brother Gunnar Golmen's super-soldier technology after suffering a nervous breakdown.