Thor (1966) #436
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Vowing to serve his country any way he could, young Steve Rogers took the super soldier serum to become America's one-man army. Fighting for the red, white and blue for over 60 years, Captain America is the living, breathing symbol of freedom and liberty.
Despondent and hopeless after it was discovered that she was not, in fact, Spider-Woman, Mary MacPherran encountered Doctor Doom, who offered her a chance to become superpowered in exchange for joining his army, to which Mary readily agreed, and Doom transformed her into Titania.